Product ID:HIGH FLASH C R U R0-033-02
MSDS Date:09/30/1987
FSC:8010
NIIN:00N017270
MSDS Number: BKSFZ

CRAWFORD LABORATORIES INC

4165 SOUTH EMERALD AVE
CHICAGO, IL 60609
US

Emergency Phone: 312-433-1307

Info Phone: 312-376-7132

Cage: DO165

CRAWFORD LABORATORIES, INC

CHICAGO, IL 60609 US

Telephone: 312-376-7132

Cage: 5V430

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 20-50%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 20-50%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

QUANTITIES OF ALCOHOL HAVE BEEN CONSUMED,

RTECS: 9999999ZZ

SUBJECT TURNS RED IN THE FACE/CHEST, & EXPERIENCE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: HEADACHE, DIZZINESS,
NAUSEA, & LOSS OF CONSCIOUSNESS. EYE: IRRITATION. INGEST: MUCOUS
MEMBRANES IRRITATION & VOMITING. SKIN: DEFATTING & DRYING WHICH MAY
RESULT IN IRRITATION, DERMATITIS & SENSITIZATION AFTER REPEATED
CONTACT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:CHOLOCARBON/CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB
ANIMALS & MAY HAVE A SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G.
EPINEPHRINE) MAY BE CONT RAINDICATED EXCEPT FOR LIFE-SUSTAINING
MEASURES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO
CHLOROCARBONS/CFC'S .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: FLUSH W/PLENTY OF FRESH WATER FOR AT LEAST 15 MIN WHILE
HOLDING EYELIDS OPEN. GET MED ATTN. INHAL: REMOVE TO FRESH AIR &
PROVIDE O*2 IF BRTHG IS DFCLT. GIVE ARTF RESP IF NOT BRTHG. GET MED
ATTN. NEVER GIVE LIQUID TO AN UNCON PERSON. INGEST: DO NOT INDUCE
VOMIT. IF VOMIT OCCURS SPONT, KEEP HEAD BELOW HIPS TO PVNT ASPIR OF
LIQUID INTO THE LUNGS. GET MED ATTN. NEVER GIVE LIQUID TO AN (SUPP
DATA)

Flash Point Method:SCC
Flash Point:144F,62C
Lower Limits:3%
Extinguishing Media:FOAM, CO*2, OR DRY CHEMICAL.
Fire Fighting Procedures:WATER MAY BE USED TO KEEP EXPOSED CONTRS COOL,
& TO KEEP FLAMM STRUCTURES WET. DO NOT ENTER FIRE AREA W/O PROPER
PROT BECAUSE HAZ DECOMP PRODS MAY (SUPP DATA)
Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A COMBUSTIBLE
LIQUID FIRE. SEALED CONTRS MAY EXPLODE IF OVERHEATED. THERMAL
DECOMP PRODUCTS MAY INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. HANDLING
EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. SOAK UP WITH AN
ABSORBANT & PLACE IN NON-LEAKING CONTAINERS. SEAL TIGHTLY FOR
PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL/DRY PLACE IN BUILDINGS
DESIGNED FOR THE STORAGE OF COMBUST LIQUIDS. IF EXPOSURE LEVEL HAS
BEEN EXCEEDED, & MODERATE TO LARGE (ING 3)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR
RESPIRATORS.
Ventilation:ADEQUATE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES
Other Protective Equipment:HAVE EYE BATH AVAILABLE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: BE PRESENT. WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND
SCBA & FULL PROTECTIVE EQUIPMENT . FIRST AID PROC: UNCON PERSON.
SKIN: FLUSH W/WATER WHILE REMOVING CONTAM CLTHG/SHOES. FOLL OW BY
WASHING WITH SOAP & WATER. DO NOTREUSE CLTHG/SHOES UNTIL CLEANED.
IF IRRITATION PERSISTS, GET MED ATTN.

HCC:V4
Boiling Pt:B.P. Text:124F,51C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:1.047
Evaporation Rate & Reference:3.4 (N-BUTYL ACETATE)
Appearance and Odor:CLEAR LIQUID.
Percent Volatiles by Volume:45.7

Stability Indicator/Materials to Avoid:YES
MAY BE INCOMPATIBLE WITH STRONG OXIDIZING AGENTS & STRONG ALKALIES.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAMES. ALSO,
AIRCRAFT TRANSPORT MUST BE IN STRICT ACCORDANCE W/APPLICABLE
REGULATION
Hazardous Decomposition Products:INCOMPLETE COMBUSTION MAY FORM HIGHLY
POISONOUS CARBON MONOXIDE & OTHER TOXIC GASES. HCL AND PHOSGENE .

Waste Disposal Methods:DISPOSAL MUST BE I/A/W CURRENT LOCAL, STATE, AND
FEDERAL REGULATIONS. CONTACT AN APPROVED DISPOSAL FACILITY.

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.